163731
CAS Number
3240-34-4Grade
Highly PurifiedMolecular Formula
C10H11IO4Molecular Weight
322.10000000000002274EU Commodity Code
38220090Shipping Temp
Blue IceStorage Temp
-20°C(Diacetoxyiodo)benzene
(Dihydroxyiodo)benzene; (Diacetoxyiodo)benzene; BAIB; Bis(acetato)phenyliodine; Bis(acetato-κO)phenyliodine; Diacetoxy(phenyl)iodine; Iodobenzene Diacetate; Iodophenyl Diacetate; Iodosobenzene Diacetate; Iodosylbenzene Diacetate; NSC 226375; NSC 23801; PIDA; Phenyliodine Diacetate; Phenyliodine(III) Diacetate; Phenyliodo Diacetate; Phenyliodonium Diacetate; Phenyliodoso Acetate; Phenyliodoso Diacetate; Phenyliodosyl Diacetate; [Bis(acetoxy)iodo]benzene; Iodosodiacetate Benzene;
(Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic acid into the corresponding aldehydes, ketones and nitriles.
Solubility
DMSO, Methanol
Stability
Light and Moisture sensitive
Storage and Stability
May be stored at RT for short-term only. Long-term storage is recommended at -20°C. For maximum recovery of product, centrifuge the original vial prior to removing the cap.
Intended for research use only. Not for use in human, therapeutic, or diagnostic applications.
References
Telvekar, V.N., et al.: Synlett., 2778 (2012); Liu, W.B., et al.: Beilstein. J. Org. Chem., 8, 244 (2012);USBio References
No references available