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261441 Allylpalladium(II) Chloride Dimer CAS: 12012-95-2

Specifications
CAS Number
12012-95-2
Grade
Highly Purified
MDL Number
MFCD00044874
Molecular Formula
C₆H₁₀Cl₂Pd₂
Molecular Weight
365.89
EU Commodity Code
38220090
Shipping Temp
RT
Storage Temp
4°C
Bis(allyl)dichlorodipalladium(II); Di-ì-chlorobis[(ç-allyl)palladium(II)]

Allylpalladium(II) chloride dimer is a homogeneous catalyst that can be used for the asymmetric synthesis of organosilicon compounds. It is an allylation agent and has been shown to react with certain nitrogen-containing compounds to form a palladium nitride complex. This compound is also a good transport agent, due to its high solubility in organic solvents. Allylpalladium(II) chloride dimer has been shown to be effective in the production of cancer chemotherapeutic agents, including chlorambucil, as well as anti-inflammatory drugs such as ibuprofen. This catalyst has also been used for cross-coupling reactions with alkyl bromides and iodides. A major drawback of this catalyst is that it often leads to an isolated yield of the product, which can be improved by using a solvent or by adding water or alcohols.

Synonyms
Bis(allyl)dichlorodipalladium(II); Di-ì-chlorobis[(ç-allyl)palladium(II)]
CAS No
12012-95-2
Molecular Formula
C₆H₁₀Cl₂Pd₂
Molecular Weight
365.89
Purity
≥97%
Appearance
Yellow-green to orange solid
Melting Point
120°C (lit)
1H NMR Spectrum
Conforms to structure
Storage and Stability
May be stored at RT for short-term only. Long-term storage is recommended at 4°C. For maximum recovery of product, centrifuge the original vial prior to removing the cap.
Important Note
This product as supplied is intended for research use only, not for use in human, therapeutic or diagnostic applications without the expressed written authorization of United States Biological.
Toxicity and Hazards
 All products should be handled by qualified personnel only, trained in laboratory procedures.
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